Synthesis and Property of Planar-chiral Cyclopentadienyl-ruthenium Complexes

Synthesis and Property of Planar-chiral Cyclopentadienyl-ruthenium Complexes

The first enantiomerically pure planar-chiral cyclopentadienyl-ruthenium complexes, [CpnRu(benzene)]PF6, were synthesized (CpnH; unsymmetricaly trisubstituted cyclopentadiene), and by a photo reaction with CH3CN converted to [CpnRu(CH3CN)3]PF6, which was transformed into planar-chiral [CpnRu(arene)]...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 1996-08, Vol.25 (8), p.677-678
Hauptverfasser: Komatsuzaki, Nobuko, Uno, Mitsunari, Kikuchi, Hidetoshi, Takahashi, Shigetoshi
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The first enantiomerically pure planar-chiral cyclopentadienyl-ruthenium complexes, [CpnRu(benzene)]PF6, were synthesized (CpnH; unsymmetricaly trisubstituted cyclopentadiene), and by a photo reaction with CH3CN converted to [CpnRu(CH3CN)3]PF6, which was transformed into planar-chiral [CpnRu(arene)]PF6 by a ligand exchange reaction.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1996.677