Observation of a Novel Fluorescent Dimer of Zinc Tetrasulphonatophthalocyanine

Zinc(II) tetrasulphonatophthalocyanine (ZnPcS4−) exhibited a new absorption band (λmax 699 nm) at the longer wavelength side of the monomer absorption band in 1:49 aqueous acetonitrile. Irradiation of the new band exerted an emission (690–730 nm, λmax 710 nm) different from the monomer fluorescence....

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Veröffentlicht in:Chemistry letters 1996-05, Vol.25 (5), p.345-346
Hauptverfasser: Kaneko, Yuji, Arai, Tatsuo, Tokumaru, Katsumi, Matsunaga, Daisaku, Sakuragi, Hirochika
Format: Artikel
Sprache:eng
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Zusammenfassung:Zinc(II) tetrasulphonatophthalocyanine (ZnPcS4−) exhibited a new absorption band (λmax 699 nm) at the longer wavelength side of the monomer absorption band in 1:49 aqueous acetonitrile. Irradiation of the new band exerted an emission (690–730 nm, λmax 710 nm) different from the monomer fluorescence.The new absorption and emission were ascribed to a novel type of ZnPcS4− dimer.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1996.345