Syntheses and Structures of Novel Optically Active Dinuclear Copper(II) Complexes of Structurally Reinforced Macrocyclic Polyamines

Syntheses and Structures of Novel Optically Active Dinuclear Copper(II) Complexes of Structurally Reinforced Macrocyclic Polyamines

Optically active μ-chloro and μ-hydroxo dinuclear copper(II) complexes of structurally reinforced chiral 18-membered azamacrocycle (2S,8S,11S,17S)-2,8,11,17-tetraisobutyl-1,4,7,10,13,16-hexaazatricyclo[14. 2. 2. 27,10]docosane and 20-membered one (2S,9S,12S,19S)-2,9,12,19-tetraisobutyl-1,4,8,l1,14,1...

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Veröffentlicht in:Chemistry letters 1996-02, Vol.25 (2), p.153-154
Hauptverfasser: Seki, Yoshio, Miyake, Hiroyuki, Kojima, Yoshitane
Format: Artikel
Sprache:eng
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Zusammenfassung:Optically active μ-chloro and μ-hydroxo dinuclear copper(II) complexes of structurally reinforced chiral 18-membered azamacrocycle (2S,8S,11S,17S)-2,8,11,17-tetraisobutyl-1,4,7,10,13,16-hexaazatricyclo[14. 2. 2. 27,10]docosane and 20-membered one (2S,9S,12S,19S)-2,9,12,19-tetraisobutyl-1,4,8,l1,14,18-hexaazatricyclo [16. 2. 2. 28,11] tetracosane obtained by BH3 reduction from structurally constrained macrocyclic pseudopeptides were newly synthesized and characterized.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1996.153