Development of Novel Hemilabile Segphos P–P=O Ligands

Development of Novel Hemilabile Segphos P–P=O Ligands

Development of novel chiral hemilabile Segphos P–P=O ligands is described. The ligands are examined for enantioselective Pd-catalyzed allylic alkylation of cyclic allylic acetates.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 2007, Vol.55(6), pp.955-956
Hauptverfasser: Fukuda, Yoshimasa, Kondo, Kazuhiro, Aoyama, Toyohiko
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Sprache:eng
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chiral hemilabile P–P=O ligand
cyclic allylic acetate
enantioselective Pd-catalyzed allylic alkylation
Segphos
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container_title Chemical & pharmaceutical bulletin
container_volume 55
creator Fukuda, Yoshimasa
Kondo, Kazuhiro
Aoyama, Toyohiko
description Development of novel chiral hemilabile Segphos P–P=O ligands is described. The ligands are examined for enantioselective Pd-catalyzed allylic alkylation of cyclic allylic acetates.
doi_str_mv 10.1248/cpb.55.955
format Article
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source J-STAGE Free; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry
subjects chiral hemilabile P–P=O ligand
cyclic allylic acetate
enantioselective Pd-catalyzed allylic alkylation
Segphos
title Development of Novel Hemilabile Segphos P–P=O Ligands
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