Development of Novel Hemilabile Segphos P–P=O Ligands

Development of novel chiral hemilabile Segphos P–P=O ligands is described. The ligands are examined for enantioselective Pd-catalyzed allylic alkylation of cyclic allylic acetates.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 2007, Vol.55(6), pp.955-956
Hauptverfasser:	Fukuda, Yoshimasa, Kondo, Kazuhiro, Aoyama, Toyohiko
Format:	Artikel
Sprache:	eng
Schlagworte:	chiral hemilabile P–P=O ligand cyclic allylic acetate enantioselective Pd-catalyzed allylic alkylation Segphos
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Beschreibung
Zusammenfassung:	Development of novel chiral hemilabile Segphos P–P=O ligands is described. The ligands are examined for enantioselective Pd-catalyzed allylic alkylation of cyclic allylic acetates.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.55.955