Dimerization of 2, 5-Dihydroxybenzoquinones in Water

2, 5-Dihydroxybenzoquinones, when heated in water, react to form different types of compounds through dimerization. The features of this unique reaction were clarified using a model compound, 2, 5-dihydroxy-3-methyl-benzoquinone. The structures of the products were established by X-ray analysis and...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1998/08/15, Vol.46(8), pp.1229-1234
Hauptverfasser: KIUCHI, Fumiyuki, TAKASHIMA, Hiromi, TSUDA, Yoshisuke
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container_title Chemical & pharmaceutical bulletin
container_volume 46
creator KIUCHI, Fumiyuki
TAKASHIMA, Hiromi
TSUDA, Yoshisuke
description 2, 5-Dihydroxybenzoquinones, when heated in water, react to form different types of compounds through dimerization. The features of this unique reaction were clarified using a model compound, 2, 5-dihydroxy-3-methyl-benzoquinone. The structures of the products were established by X-ray analysis and spectroscopic means.
doi_str_mv 10.1248/cpb.46.1229
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subjects 1, 4-dibenzofurandione
2, 5-dihyroxybenzoquinone
Chemistry
dimerization
Exact sciences and technology
furanylidene benzofuranone
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
X-ray analysis
title Dimerization of 2, 5-Dihydroxybenzoquinones in Water
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