Dimerization of 2, 5-Dihydroxybenzoquinones in Water

2, 5-Dihydroxybenzoquinones, when heated in water, react to form different types of compounds through dimerization. The features of this unique reaction were clarified using a model compound, 2, 5-dihydroxy-3-methyl-benzoquinone. The structures of the products were established by X-ray analysis and...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1998/08/15, Vol.46(8), pp.1229-1234
Hauptverfasser: KIUCHI, Fumiyuki, TAKASHIMA, Hiromi, TSUDA, Yoshisuke
Format: Artikel
Sprache:eng
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Zusammenfassung:2, 5-Dihydroxybenzoquinones, when heated in water, react to form different types of compounds through dimerization. The features of this unique reaction were clarified using a model compound, 2, 5-dihydroxy-3-methyl-benzoquinone. The structures of the products were established by X-ray analysis and spectroscopic means.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.46.1229