EXPLANATION FOR STEREOSELECTIVITY OF THS CIS-DIHYDROXYLATION OF CIS-3, 5-DISUBSTITUTED CYCLOPENTENES

EXPLANATION FOR STEREOSELECTIVITY OF THS CIS-DIHYDROXYLATION OF CIS-3, 5-DISUBSTITUTED CYCLOPENTENES

Stereoselectivity of the cis-dihydroxylation of cis-3, 5-disubstituted cyclopentenes has been found to depend on the conformation of cyclopenetenes and has been explained by both steric and Cieplak effects.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1994/12/15, Vol.42(12), pp.2653-2655
Hauptverfasser: KATAGIRI, Nobuya, ITO, Yumiko, KITANO, Kenji, TOYOTA, Akemi, KANEKO, Chikara
Format: Artikel
Sprache:eng
Schlagworte:
carbocyclic nucleoside
Cieplak effect
cis-3, 5-disubstituted
cis-dihydroxylation
cyclopentene
stereoselectivity
steric effect
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Beschreibung
Zusammenfassung:Stereoselectivity of the cis-dihydroxylation of cis-3, 5-disubstituted cyclopentenes has been found to depend on the conformation of cyclopenetenes and has been explained by both steric and Cieplak effects.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.42.2653