BARBIER-TYPE REACTIONS OF ARYL HELIDES WITH KETONES MEDIATED BY SAMARIUM DIIODIDE

BARBIER-TYPE REACTIONS OF ARYL HELIDES WITH KETONES MEDIATED BY SAMARIUM DIIODIDE

Barbier-type reaction of aryl halides with ketones took place on treatment with samarium diiodide in benzene containing 10 % hexamethylphosphoric triamide (HMPA). The reaction involves an aryl samarium as an intermediate.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1994/10/15, Vol.42(10), pp.2190-2192
Hauptverfasser: KUNISHIMA, Munetaka, HIOKI, Kazuhito, KONO, Kazuhiro, SAKUMA, Takayuki, TANI, Shohei
Format: Artikel
Sprache:eng
Schlagworte:
aryl samarium
Barbier reaction
samarium diiodide
tert-alcohol
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Beschreibung
Zusammenfassung:Barbier-type reaction of aryl halides with ketones took place on treatment with samarium diiodide in benzene containing 10 % hexamethylphosphoric triamide (HMPA). The reaction involves an aryl samarium as an intermediate.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.42.2190