ABSOLUTE STEREOSTRUCTURES OF PAEONISUFFRONE AND PAEONISUFFRAL, TWO NEW LABILE MONOTERPENES, FROM CHINESE MOUTAN CORTEX

ABSOLUTE STEREOSTRUCTURES OF PAEONISUFFRONE AND PAEONISUFFRAL, TWO NEW LABILE MONOTERPENES, FROM CHINESE MOUTAN CORTEX

Two new labile monoterpenes named paeonisuffrone and paeonisuffral were isolated from Chinese Moutan Cortex, the dried root of Paeonia suffruticosa ANDREWS. The absolute stereostructures of peaonisuffrone and paeonisuffral were elucidated on the basis of chemical and physicochemical evidence which i...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1993/03/15, Vol.41(3), pp.630-632
Hauptverfasser: YOSHIKAWA, Masayuki, HARADA, Emiko, KAWAGUCHI, Atsuhiro, YAMAHARA, Johji, MURAKAMI, Nobutoshi, KITAGAWA, Isao
Format: Artikel
Sprache:eng
Schlagworte:
Analytical, structural and metabolic biochemistry
Biological and medical sciences
Fundamental and applied biological sciences. Psychology
Mosher's method modifid
Moutan Cortex
Other biological molecules
Paeonia suffruticosa
Paeoniaceae
peaonisuffrone, paeonisuffral
Terpenes, steroids. Hormones
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Zusammenfassung:Two new labile monoterpenes named paeonisuffrone and paeonisuffral were isolated from Chinese Moutan Cortex, the dried root of Paeonia suffruticosa ANDREWS. The absolute stereostructures of peaonisuffrone and paeonisuffral were elucidated on the basis of chemical and physicochemical evidence which included the application of a modified Mosher's method and lipase catalyzed debenzoylation.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.41.630