Chemical Transformation of Terpenoids. VIII. Anodic Oxidation of Geranyl Acetate

Constant-current electrolysis of geranyl acetate (2) in CH3CN-H2O afforded eight oxidation products (3-10) which were presumed to be formed through initial oxidation of the double bond at C6-C7. Based on the results of electrolysis of 2 in CH3CN-H218O, we have found that the oxygen atom(s) in the pr...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 1991/05/25, Vol.39(5), pp.1302-1304
Hauptverfasser:	SHIBUYA, Hirotaka, MURAKAMI, Nobutoshi, SHIMADA, Fukiko, KITAGAWA, Isao
Format:	Artikel
Sprache:	eng
Schlagworte:	anodic oxidation Chemistry constant-current electrolysis Electrochemistry Exact sciences and technology General and physical chemistry geraniol geranyl acetate geranyl acetate 6, 7-epoxide Kinetics and mechanism of reactions water-18O
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Zusammenfassung:	Constant-current electrolysis of geranyl acetate (2) in CH3CN-H2O afforded eight oxidation products (3-10) which were presumed to be formed through initial oxidation of the double bond at C6-C7. Based on the results of electrolysis of 2 in CH3CN-H218O, we have found that the oxygen atom(s) in the products (3-10) is(are) derived from water used as the reaction medium.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.39.1302