Convenient Synthesis of the Epoxy Fragment of Azinomycin B

A new convenient route for asymmetric synthesis of the epoxy fragment of azinomycin B by Sharpless asymmetric epoxidation of secondary allylic alcohol is described.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1994/02/15, Vol.42(2), pp.285-288
Hauptverfasser: KONDA, Yaeko, MACHIDA, Tomomi, SASAKI, Tomomitsu, TAKEDA, Kazuyoshi, TAKAYANAGI, Hiroaki, HARIGAYA, Yoshihiro
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container_end_page 288
container_issue 2
container_start_page 285
container_title Chemical & pharmaceutical bulletin
container_volume 42
creator KONDA, Yaeko
MACHIDA, Tomomi
SASAKI, Tomomitsu
TAKEDA, Kazuyoshi
TAKAYANAGI, Hiroaki
HARIGAYA, Yoshihiro
description A new convenient route for asymmetric synthesis of the epoxy fragment of azinomycin B by Sharpless asymmetric epoxidation of secondary allylic alcohol is described.
doi_str_mv 10.1248/cpb.42.285
format Article
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subjects allylic alcohol
asymmetric synthesis
azinomycin B
Chemistry
Condensed matter: structure, mechanical and thermal properties
epoxide
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Organic compounds
Physics
Preparations and properties
Sharpless asymmetric epoxidation
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
X-ray
title Convenient Synthesis of the Epoxy Fragment of Azinomycin B
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