Convenient Synthesis of the Epoxy Fragment of Azinomycin B

A new convenient route for asymmetric synthesis of the epoxy fragment of azinomycin B by Sharpless asymmetric epoxidation of secondary allylic alcohol is described.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 1994/02/15, Vol.42(2), pp.285-288
Hauptverfasser:	KONDA, Yaeko, MACHIDA, Tomomi, SASAKI, Tomomitsu, TAKEDA, Kazuyoshi, TAKAYANAGI, Hiroaki, HARIGAYA, Yoshihiro
Format:	Artikel
Sprache:	eng
Schlagworte:	allylic alcohol asymmetric synthesis azinomycin B Chemistry Condensed matter: structure, mechanical and thermal properties epoxide Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Organic chemistry Organic compounds Physics Preparations and properties Sharpless asymmetric epoxidation Structure of solids and liquids crystallography Structure of specific crystalline solids X-ray
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Beschreibung
Zusammenfassung:	A new convenient route for asymmetric synthesis of the epoxy fragment of azinomycin B by Sharpless asymmetric epoxidation of secondary allylic alcohol is described.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.42.285