Convenient Synthesis of Allylic Sulfides and Application to Allylic Carbon-Carbon Bond Formation

Allylic sulfides were synthesized from allylic alcohols 1 using S, S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate (2) by means of a single-step reaction. The allylic sulfides were coupled with a Grignard reagent or carbanion in the presence of a catalytic amount of copper(I) bromide or palla...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 1990/09/25, Vol.38(9), pp.2357-2363
Hauptverfasser:	TSUBOYAMA, Kanoko, TAKEDA, Kazuyoshi, TORII, Katsumi, OGURA, Haruo
Format:	Artikel
Sprache:	eng
Schlagworte:	allylic sulfide carbon-carbon bond formation Chemistry copper(I) bromide cross-coupling reaction Exact sciences and technology Organic chemistry palladium S, S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate
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Beschreibung
Zusammenfassung:	Allylic sulfides were synthesized from allylic alcohols 1 using S, S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate (2) by means of a single-step reaction. The allylic sulfides were coupled with a Grignard reagent or carbanion in the presence of a catalytic amount of copper(I) bromide or palladium(0).
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.38.2357