Photocyclization of Enamides. XXVIII

A formal total synthesis of (±)-deserpidine (1) was accomplished by preparing the known synthetic precursors, two hydroxyesters 19 and 20, via a route involving regioselective formation of the 18-methoxyenone 10a followed by regioselective C-acylation of the enone 10a.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 1989-04, Vol.37 (4), p.901
Hauptverfasser:	NAITO, Takeaki, HIRATA, Yumiko, MIYATA, Okiko, NINOMIYA, Ichiya, INOUE, Masatoshi, KAMIICHI, Katsuhisa
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A formal total synthesis of (±)-deserpidine (1) was accomplished by preparing the known synthetic precursors, two hydroxyesters 19 and 20, via a route involving regioselective formation of the 18-methoxyenone 10a followed by regioselective C-acylation of the enone 10a.
ISSN:	0009-2363 1347-5223