Synthesis of Macrocyclic Terpenoids by Intramolecular Cyclization. XI. Total Synthesis of Zerumbone

Zerumbone (1), an eleven-membered ring sesquiterpene isolated from Zingiber zerumbet, was synthesized by means of an intramolecular Wittig-type reaction of the keto-phosphonate 2.

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 1987/10/25, Vol.35(10), pp.4039-4042
Hauptverfasser:	KODAMA, MITSUAKI, SHIOBARA, YOSHINORI, SUMITOMO, HISAKO, MITANI, KAZUKO, UENO, KUMIKO
Format:	Artikel
Sprache:	eng
Schlagworte:	20-octamethyl-2 21-cyclodocosahexaene-1 Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry eleven-membered ring formation Exact sciences and technology humulane sesquiterpene intramolecular Wittig reaction Organic chemistry Preparations and properties synthesis Terpenoids zerumbone
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Beschreibung
Zusammenfassung:	Zerumbone (1), an eleven-membered ring sesquiterpene isolated from Zingiber zerumbet, was synthesized by means of an intramolecular Wittig-type reaction of the keto-phosphonate 2.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.35.4039