Synthesis and Some Properties of 2-Azathiabenzene 1-Oxides

Syntheses of 1-methyl-2-azathiabenzene 1-oxide and its 5-methyl derivative are described. The physical (1H-nuclear magnetic resonance (NMR) and13C-NMR spectra) and chemical properties (deuteration, bromination, and nitration) suggest that 1-methyl-2-azathiabenzene 1-oxides are best considered as cyc...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 1984/08/25, Vol.32(8), pp.3028-3035
Hauptverfasser:	IKEDA, MASAZUMI, TSUBOUCHI, HIDETSUGU, TSUNEKAWA, MASAYOSHI, KONDO, HIROSHI, TAMURA, YASUMITSU
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Organic chemistry Preparations and properties thiabenzene 1-oxide
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Zusammenfassung:	Syntheses of 1-methyl-2-azathiabenzene 1-oxide and its 5-methyl derivative are described. The physical (1H-nuclear magnetic resonance (NMR) and13C-NMR spectra) and chemical properties (deuteration, bromination, and nitration) suggest that 1-methyl-2-azathiabenzene 1-oxides are best considered as cyclic sulfur ylides.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.32.3028