Electrochemical Detector for High-Performance Liquid Chromatography. VI. Application of a Twin Electrochemical Detector
The fundamental characteristics of a twin electrochemical detector were evaluated to investigate its suitability as a detector for high-performance liquid chromatography. This novel detector was proved to have the following advantages compared to the conventional three-electrode detector. 1) Simulta...
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| Veröffentlicht in: | Chemical & pharmaceutical bulletin 1983/10/25, Vol.31(10), pp.3571-3578 |
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| container_title | Chemical & pharmaceutical bulletin |
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| creator | HIROSHIMA, OSAMU IKENOYA, SATORU NAITOH, TOSHIHIKO KUSUBE, KENICHI OHMAE, MASAHIKO KAWABE, KIYOSHI ISHIKAWA, SEIJI HOSHIDA, HARUHIKO KURAHASHI, TATSUO |
| description | The fundamental characteristics of a twin electrochemical detector were evaluated to investigate its suitability as a detector for high-performance liquid chromatography. This novel detector was proved to have the following advantages compared to the conventional three-electrode detector. 1) Simultaneous determination of reduced and oxidized species is possible, 2) the stability of the electrode is improved by applying a larger potential to the other electrode, 3) the specificity of detection is improved by the re-electrolysis at the second electrode of the reaction product produced at the first electrode, and 4) specific detection of the post-discharging materials and sensitive detection are possible by using appropriate operating circuits. |
| doi_str_mv | 10.1248/cpb.31.3571 |
| format | Article |
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This novel detector was proved to have the following advantages compared to the conventional three-electrode detector. 1) Simultaneous determination of reduced and oxidized species is possible, 2) the stability of the electrode is improved by applying a larger potential to the other electrode, 3) the specificity of detection is improved by the re-electrolysis at the second electrode of the reaction product produced at the first electrode, and 4) specific detection of the post-discharging materials and sensitive detection are possible by using appropriate operating circuits.</abstract><cop>Tokyo</cop><pub>The Pharmaceutical Society of Japan</pub><doi>10.1248/cpb.31.3571</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | J-STAGE Free; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry |
| subjects | Analytical chemistry Chemistry Exact sciences and technology General, instrumentation monoamine |
| title | Electrochemical Detector for High-Performance Liquid Chromatography. VI. Application of a Twin Electrochemical Detector |
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