Bicyclo [3. 3. 1] nonanes as Synthetic Intermediates. V. The Baeyer-Villiger Oxidation of Bicyclo [3. 3. 1] nonane-3, 7-dione and Its Congeners

Bicyclo [3. 3. 1] nonanes as Synthetic Intermediates. V. The Baeyer-Villiger Oxidation of Bicyclo [3. 3. 1] nonane-3, 7-dione and Its Congeners

The Baeyer-Villiger oxidation, which is known to be unsuccessful with the bicyclo [3. 3. 1] nonan-3-one system, was shown to proceed smoothyl with the 3, 7-dioxo compounds 1 and 6. The particular steric factors affecting the reaction of these and related systems are discussed.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1979/03/25, Vol.27(3), pp.824-828
Hauptverfasser: MOMOSE, TAKEFUMI, ATARASHI, SHOHGO
Format: Artikel
Sprache:eng
Schlagworte:
Robinson-Schopf condensation
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Zusammenfassung:The Baeyer-Villiger oxidation, which is known to be unsuccessful with the bicyclo [3. 3. 1] nonan-3-one system, was shown to proceed smoothyl with the 3, 7-dioxo compounds 1 and 6. The particular steric factors affecting the reaction of these and related systems are discussed.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.27.824