Studies on the Constituents of Ophiopogonis Tuber. III. On the Structure of Ophiopogonin D

The chemical structure of ophiopogonin D, a glycoside isolated from the tuber of Ophiopogon japonicus KER-GAWLER var. genuinus MAXIM.(Liliaceae) was established to be ruscogenin (1)-[α-L-rhamnopyranosyl (1rham→2fue)][D-xylopyranosyl (1xyl→3fue)]β-D-fucopyranoside (Ia). Ophiopogonin D is one of spiro...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1973/02/25, Vol.21(2), pp.308-311
Hauptverfasser: TADA, AKIHIRO, KOBAYASHI, MASAKI, SHOJI, JUNZO
Format: Artikel
Sprache:eng
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Zusammenfassung:The chemical structure of ophiopogonin D, a glycoside isolated from the tuber of Ophiopogon japonicus KER-GAWLER var. genuinus MAXIM.(Liliaceae) was established to be ruscogenin (1)-[α-L-rhamnopyranosyl (1rham→2fue)][D-xylopyranosyl (1xyl→3fue)]β-D-fucopyranoside (Ia). Ophiopogonin D is one of spirostane type glycosides whose sugar moietylinks to the hydroxyl group other than C3 hydroxyl group of the aglycone.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.21.308