Formic Acid Reduction. VIII. Reduction of Nitrosobenzenes to Azoxybenzenes

Formic Acid Reduction. VIII. Reduction of Nitrosobenzenes to Azoxybenzenes

TMAF, 5HCO2H·2N (CH3)3 was found to be efficient reagent for reduction of nitrosobenzenes to azoxybenzenes. Reductions of a variety of nitrosobenzenes revealed the usefulness of the method for the preparation of azoxybenzenes. Comments on the course of the reduction are given.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1970/11/25, Vol.18(11), pp.2146-2150
Hauptverfasser: SEKIYA, MINORU, TAKAYAMA, SHUICHI
Format: Artikel
Sprache:eng
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Zusammenfassung:TMAF, 5HCO2H·2N (CH3)3 was found to be efficient reagent for reduction of nitrosobenzenes to azoxybenzenes. Reductions of a variety of nitrosobenzenes revealed the usefulness of the method for the preparation of azoxybenzenes. Comments on the course of the reduction are given.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.18.2146