Usnic Acid. I. Methyldihydrousnic Acid

Methyldihydrousnic acid was obtained by methylation of dihydrousnic acid and itsconstitution was elucidated as (I). The result that 3'-methyl-2', 6'-dihydroxyacetophenone was obtained from methyldihydrousnic acid indicates that the resorcinol type of compound is derived from B-ring of...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1962/07/25, Vol.10(7), pp.603-607
Hauptverfasser: Takahashi, Kotaro, Miyashita, Shuichi
Format: Artikel
Sprache:eng
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Zusammenfassung:Methyldihydrousnic acid was obtained by methylation of dihydrousnic acid and itsconstitution was elucidated as (I). The result that 3'-methyl-2', 6'-dihydroxyacetophenone was obtained from methyldihydrousnic acid indicates that the resorcinol type of compound is derived from B-ring of (I). This result also presents the experimental proof of formation of 3'-methyl-2', 6'-dihydroxyacetophenone, one of resorcinol type of compound, from B-ring of dihydrousnic acid.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.10.603