Efficient Reductive Deoximation by Tungsten(VI) Chloride (WCl6) or Molybdenum(V) Chloride (MoCl5) in the Presence of Zn Powder in CH3CN
Tungsten(VI) chloride (WCl6) or molybdenum(V) chloride (MoCl5) in the presence of zinc powder in CH3CN provides an efficient and facile procedure for the deprotection of oximes to their corresponding aldehydes and ketones in high yields.
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2002-08, Vol.75 (8), p.1761-1764 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Tungsten(VI) chloride (WCl6) or molybdenum(V) chloride (MoCl5) in the presence of zinc powder in CH3CN provides an efficient and facile procedure for the deprotection of oximes to their corresponding aldehydes and ketones in high yields. |
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| ISSN: | 0009-2673 1348-0634 |
| DOI: | 10.1246/bcsj.75.1761 |