Trigonal-Bipyramidal Geometry in a Cobalt(II) Complex with an Unsymmetrical Tripodal Ligand

Trigonal-Bipyramidal Geometry in a Cobalt(II) Complex with an Unsymmetrical Tripodal Ligand

A cobalt(II) complex with bis[2-(3,5-dimethylpyrazol-1-yl)ethyl][(pyrazol-1-yl)methyl]amine (bppa), [CoCl(bppa)][B(C6H5)4]·C2H5OH, was synthesized and characterized by measurements of the magnetic moment and the electronic spectra. The X-ray crystal structure shows that the compound has a distorted...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2001-11, Vol.74 (11), p.2131-2132
Hauptverfasser: Lim, Jong-Wan, Mikuriya, Masahiro, Sakiyama, Hiroshi
Format: Artikel
Sprache:eng
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Zusammenfassung:A cobalt(II) complex with bis[2-(3,5-dimethylpyrazol-1-yl)ethyl][(pyrazol-1-yl)methyl]amine (bppa), [CoCl(bppa)][B(C6H5)4]·C2H5OH, was synthesized and characterized by measurements of the magnetic moment and the electronic spectra. The X-ray crystal structure shows that the compound has a distorted trigonal bipyramid with a N4Cl coordination environment.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.74.2131