cis-Dioxomolybdenum(VI) Complex with a Tripod-Like Tetradentate Ligand, N′, N′-Bis(2-hydroxy-3,5-dimethylbenzyl)-N, N-dimethylethylenediamine

cis-Dioxomolybdenum(VI) Complex with a Tripod-Like Tetradentate Ligand, N′, N′-Bis(2-hydroxy-3,5-dimethylbenzyl)-N, N-dimethylethylenediamine

A cis-dioxomolybdenum(VI) complex with N′, N′-bis(2-hydroxy-3,5-dimethylbenzyl)-N, N-dimethylethylenediamine (H2L), cis-[MoO2(L)], was synthesized and characterized by measurements of NMR, infrared, and electronic spectra. The X-ray crystal structure shows that the compound has a distorted octahedra...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2002-09, Vol.75 (9), p.2011-2012
Hauptverfasser: Lim, Jong-Wan, Park, Yu-Chul, Mikuriya, Masahiro
Format: Artikel
Sprache:eng
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Zusammenfassung:A cis-dioxomolybdenum(VI) complex with N′, N′-bis(2-hydroxy-3,5-dimethylbenzyl)-N, N-dimethylethylenediamine (H2L), cis-[MoO2(L)], was synthesized and characterized by measurements of NMR, infrared, and electronic spectra. The X-ray crystal structure shows that the compound has a distorted octahedral geometry with an N2O4 coordination environment.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.75.2011