Formation of a Trinuclear Mercury(II) Complex Mediated by a Phosphorane
Phenacylidenetriphenylphosphorane reacts with HgI2 in 2 : 3 molar ratio to form a novel trinuclear iodobridged symmetrical complex whose structure has been elucidated by IR, multinuclear NMR, and X-ray crystallography. The Hg···Hg distance [3.648(1) Å] indicates a negligible bonding interaction betw...
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 1999-01, Vol.72 (1), p.33 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Phenacylidenetriphenylphosphorane reacts with HgI2 in 2 : 3 molar ratio to form a novel trinuclear iodobridged symmetrical complex whose structure has been elucidated by IR, multinuclear NMR, and X-ray crystallography. The Hg···Hg distance [3.648(1) Å] indicates a negligible bonding interaction between the mercury atoms. |
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| ISSN: | 0009-2673 1348-0634 |