Selective Methylation of Amines with Carbon Dioxide and H2

Put a label on it: Carbon dioxide with H2 is shown to be an efficient and selective methylation reagent for aromatic and aliphatic amines (see scheme; acac=acetylacetonate, triphos = 1,1,1‐tris(diphenylphosphanylmethyl)ethane). A variety of functionalized amines including 13C‐labelled drugs were obt...

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Veröffentlicht in:	Angewandte Chemie International Edition 2013-11, Vol.52 (46), p.12156-12160
Hauptverfasser:	Li, Yuehui, Sorribes, Iván, Yan, Tao, Junge, Kathrin, Beller, Matthias
Format:	Artikel
Sprache:	eng
Schlagworte:	homogeneous catalysis hydrogen methylation reduction ruthenium
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description	Put a label on it: Carbon dioxide with H2 is shown to be an efficient and selective methylation reagent for aromatic and aliphatic amines (see scheme; acac=acetylacetonate, triphos = 1,1,1‐tris(diphenylphosphanylmethyl)ethane). A variety of functionalized amines including 13C‐labelled drugs were obtained with good yields and functional‐group tolerance.
doi_str_mv	10.1002/anie.201306850
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subjects	homogeneous catalysis hydrogen methylation reduction ruthenium
title	Selective Methylation of Amines with Carbon Dioxide and H2
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