Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier
A poly(vinyl chloride) membrane electrode that is highly sensitive and selective for zinc ions has been developed by using tetrabutyl thiuram disulfide neutral carrier. This electrode incorporated the ionophore along with o-nitrophenyloctyl ether as a plasticizing solvent mediator and potassium tetr...
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| Veröffentlicht in: | Analytical Sciences 1994/06/10, Vol.10(3), pp.409-412 |
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| creator | KOJIMA, Ryuji KAMATA, Satsuo |
| description | A poly(vinyl chloride) membrane electrode that is highly sensitive and selective for zinc ions has been developed by using tetrabutyl thiuram disulfide neutral carrier. This electrode incorporated the ionophore along with o-nitrophenyloctyl ether as a plasticizing solvent mediator and potassium tetrakis(p-chlorophenyl)borate as anion excluder; it exhibited a linearity range of 10-1-10-6M with a Nernstian slope of 28.0mV per decade at 25±1°C. The membrane electrode showed a good response to zinc ions in the useful pH range of 3.5 to 6.5, where interferences arise only from a few transition metals such as CuII and PbII. |
| doi_str_mv | 10.2116/analsci.10.409 |
| format | Article |
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This electrode incorporated the ionophore along with o-nitrophenyloctyl ether as a plasticizing solvent mediator and potassium tetrakis(p-chlorophenyl)borate as anion excluder; it exhibited a linearity range of 10-1-10-6M with a Nernstian slope of 28.0mV per decade at 25±1°C. The membrane electrode showed a good response to zinc ions in the useful pH range of 3.5 to 6.5, where interferences arise only from a few transition metals such as CuII and PbII.</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.10.409</identifier><identifier>CODEN: ANSCEN</identifier><language>eng</language><publisher>Tokyo: The Japan Society for Analytical Chemistry</publisher><subject>Chemistry ; Electrochemistry ; Electrodes: preparations and properties ; Exact sciences and technology ; General and physical chemistry ; Ion selective electrodes ; neutral carrier ; tetrabutyl thiuram disulfide ; zinc ion ; Zinc-selective membrane electrode</subject><ispartof>Analytical Sciences, 1994/06/10, Vol.10(3), pp.409-412</ispartof><rights>The Japan Society for Analytical Chemistry</rights><rights>1994 INIST-CNRS</rights><rights>Copyright Japan Science and Technology Agency 1994</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c483t-a471298486cff7fd81460508c0d9f517f16d170e92d3e0c1d95b2549653fb2b23</citedby><cites>FETCH-LOGICAL-c483t-a471298486cff7fd81460508c0d9f517f16d170e92d3e0c1d95b2549653fb2b23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,1883,4024,27923,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4256983$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>KOJIMA, Ryuji</creatorcontrib><creatorcontrib>KAMATA, Satsuo</creatorcontrib><title>Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier</title><title>Analytical Sciences</title><description>A poly(vinyl chloride) membrane electrode that is highly sensitive and selective for zinc ions has been developed by using tetrabutyl thiuram disulfide neutral carrier. 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The membrane electrode showed a good response to zinc ions in the useful pH range of 3.5 to 6.5, where interferences arise only from a few transition metals such as CuII and PbII.</description><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Electrodes: preparations and properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Ion selective electrodes</subject><subject>neutral carrier</subject><subject>tetrabutyl thiuram disulfide</subject><subject>zinc ion</subject><subject>Zinc-selective membrane electrode</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNo9kD1PwzAQhi0EEqWwMkeCNcWfiT2iAgWpwEC7sESOc25dpWmxE6T-exyldLF1vufesx6EbgmeUEKyB93oOhg3iTXH6gyNCOMypZRn52iEFcFpxji-RFchbDAmVFI6Qotv15j0C2owrfuF5B22pdcNJM_9i99VkCyDa1bJAlqvy6491Mli7Tqvt8mTC11tXUQ-oIvdOplq7x34a3Rh41_g5niP0fLleTF9Teefs7fp4zw1XLI21TwnVEkuM2NtbitJeIYFlgZXygqSW5JVJMegaMUAG1IpUVLBVSaYLWlJ2RjdDbl7v_vpILTFZtf5XkNBOJci5lERqclAGb8LwYMt9t5ttT8UBBe9ueJorq-juThwf4zVwejaRh_GhdMUpyJTkkVsNmCb0OoVnPrat87U8J9KlBR9MhuOuOBEmLX2BTTsD9hHiFA</recordid><startdate>1994</startdate><enddate>1994</enddate><creator>KOJIMA, Ryuji</creator><creator>KAMATA, Satsuo</creator><general>The Japan Society for Analytical Chemistry</general><general>Japan Society for Analytical Chemistry</general><general>Japan Science and Technology Agency</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope></search><sort><creationdate>1994</creationdate><title>Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier</title><author>KOJIMA, Ryuji ; KAMATA, Satsuo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c483t-a471298486cff7fd81460508c0d9f517f16d170e92d3e0c1d95b2549653fb2b23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Electrodes: preparations and properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Ion selective electrodes</topic><topic>neutral carrier</topic><topic>tetrabutyl thiuram disulfide</topic><topic>zinc ion</topic><topic>Zinc-selective membrane electrode</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>KOJIMA, Ryuji</creatorcontrib><creatorcontrib>KAMATA, Satsuo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>KOJIMA, Ryuji</au><au>KAMATA, Satsuo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier</atitle><jtitle>Analytical Sciences</jtitle><date>1994</date><risdate>1994</risdate><volume>10</volume><issue>3</issue><spage>409</spage><epage>412</epage><pages>409-412</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><coden>ANSCEN</coden><abstract>A poly(vinyl chloride) membrane electrode that is highly sensitive and selective for zinc ions has been developed by using tetrabutyl thiuram disulfide neutral carrier. This electrode incorporated the ionophore along with o-nitrophenyloctyl ether as a plasticizing solvent mediator and potassium tetrakis(p-chlorophenyl)borate as anion excluder; it exhibited a linearity range of 10-1-10-6M with a Nernstian slope of 28.0mV per decade at 25±1°C. The membrane electrode showed a good response to zinc ions in the useful pH range of 3.5 to 6.5, where interferences arise only from a few transition metals such as CuII and PbII.</abstract><cop>Tokyo</cop><pub>The Japan Society for Analytical Chemistry</pub><doi>10.2116/analsci.10.409</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Analytical Sciences, 1994/06/10, Vol.10(3), pp.409-412 |
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| subjects | Chemistry Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry Ion selective electrodes neutral carrier tetrabutyl thiuram disulfide zinc ion Zinc-selective membrane electrode |
| title | Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier |
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