Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier

A poly(vinyl chloride) membrane electrode that is highly sensitive and selective for zinc ions has been developed by using tetrabutyl thiuram disulfide neutral carrier. This electrode incorporated the ionophore along with o-nitrophenyloctyl ether as a plasticizing solvent mediator and potassium tetr...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Analytical Sciences 1994/06/10, Vol.10(3), pp.409-412
Hauptverfasser:	KOJIMA, Ryuji, KAMATA, Satsuo
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry Ion selective electrodes neutral carrier tetrabutyl thiuram disulfide zinc ion Zinc-selective membrane electrode
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	A poly(vinyl chloride) membrane electrode that is highly sensitive and selective for zinc ions has been developed by using tetrabutyl thiuram disulfide neutral carrier. This electrode incorporated the ionophore along with o-nitrophenyloctyl ether as a plasticizing solvent mediator and potassium tetrakis(p-chlorophenyl)borate as anion excluder; it exhibited a linearity range of 10-1-10-6M with a Nernstian slope of 28.0mV per decade at 25±1°C. The membrane electrode showed a good response to zinc ions in the useful pH range of 3.5 to 6.5, where interferences arise only from a few transition metals such as CuII and PbII.
ISSN:	0910-6340 1348-2246
DOI:	10.2116/analsci.10.409