Newly developed acrylic copolymers for ArF photoresist

We have developed novel acrylic copolymers for ArF photoresist which have more etching durability than usual. The excellent one of those copolymers in handling contains 8- or 9-methacryloyloxy-4-oxatricyclo[5.2.1.02, 6]decan-3-one (OTDMA) and γ, γ-dimethyl-α-methylene-γ-butyrolactone (DMMB). OTDMA i...

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Veröffentlicht in:Journal of Photopolymer Science and Technology 2002, Vol.15(4), pp.535-540
Hauptverfasser: Kamon, Yoshihiro, Momose, Hikaru, Kuwano, Hideaki, Fujiwara, Tadayuki, Fujimoto, Masaharu
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container_end_page 540
container_issue 4
container_start_page 535
container_title Journal of Photopolymer Science and Technology
container_volume 15
creator Kamon, Yoshihiro
Momose, Hikaru
Kuwano, Hideaki
Fujiwara, Tadayuki
Fujimoto, Masaharu
description We have developed novel acrylic copolymers for ArF photoresist which have more etching durability than usual. The excellent one of those copolymers in handling contains 8- or 9-methacryloyloxy-4-oxatricyclo[5.2.1.02, 6]decan-3-one (OTDMA) and γ, γ-dimethyl-α-methylene-γ-butyrolactone (DMMB). OTDMA is a new methacrylic ester monomer having a lactone unit with bridged structure. DMMB introduces a lactone structure to the main chain of acrylic copolymers. It was suggested that the solubility of monomers depends on the hindrance of their polar group, and the role of the hydrophilic monomers has been discussed from the standpoint of the position of their hydrophilic parts.
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subjects acrylic copolymer
ArF photoresist
DMMB
etching durability
hydrophilic part
OTDMA
solubility
title Newly developed acrylic copolymers for ArF photoresist
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