Theory and Verify of Mensurate Cl- Ion by Flow Injection-Cathodic Potentiometric Stripping Analysis

In this paper, the theoretical equation of flow injection-cathodic potentiometric stripping analysis for Cl- ion determination was derived from theoretical analysis, and the experimental equation was summarized using multiple linear regression method. The result shows that the theoretical equation o...

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Veröffentlicht in:Applied Mechanics and Materials 2013-08, Vol.347-350, p.1192-1195
Hauptverfasser: Li, Zai Yuan, Ni, Jian Wen, Han, Zhi Jia, Li, Ying
Format: Artikel
Sprache:eng
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Zusammenfassung:In this paper, the theoretical equation of flow injection-cathodic potentiometric stripping analysis for Cl- ion determination was derived from theoretical analysis, and the experimental equation was summarized using multiple linear regression method. The result shows that the theoretical equation of flow injection-cathodic potentiometric stripping analysis for Cl- ion is: (dt/dE)max =K Ap r-1/2D2/3-1/6Vf1/2teCx-/is; that the experimental equation of multiple linear regression method is: (dt/dE)max Cl-1.86×1010Vf0.568 teC Cl-/is. The two results are similar on Vf-average flow rate, te-concentrate time, C Cl- -Cl- ion concentration and is constant current.
ISSN:1660-9336
1662-7482
1662-7482
DOI:10.4028/www.scientific.net/AMM.347-350.1192