ChemInform Abstract: Synthesis of Glutamic Acid and Highly Functionalized Pyrrolidine Derivatives by Utilizing Tunable Calcium Catalysts for Chemoselective Asymmetric 1,4-Addition and [3 + 2] Cycloaddition Reactions
The direction of calcium‐catalyzed reaction of Schiff bases with acrylic acid esters and amides depends on the structure of starting compounds leading to either glutamic acid derivatives or substituted pyrrolidines.
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| Veröffentlicht in: | ChemInform 2013-10, Vol.44 (41), p.no-no |
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| creator | Hut'ka, Martin Tsubogo, Tetsu Kobayashi, Shu |
| description | The direction of calcium‐catalyzed reaction of Schiff bases with acrylic acid esters and amides depends on the structure of starting compounds leading to either glutamic acid derivatives or substituted pyrrolidines. |
| doi_str_mv | 10.1002/chin.201341027 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Acrylics addition reactions aminocarboxylic acids (hydrazinocarboxylic acids) and esters (acyclic compounds) Calcium Chemical industry cycloaddition reactions diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) pyrrole derivatives |
| title | ChemInform Abstract: Synthesis of Glutamic Acid and Highly Functionalized Pyrrolidine Derivatives by Utilizing Tunable Calcium Catalysts for Chemoselective Asymmetric 1,4-Addition and [3 + 2] Cycloaddition Reactions |
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