ChemInform Abstract: Synthesis of Glutamic Acid and Highly Functionalized Pyrrolidine Derivatives by Utilizing Tunable Calcium Catalysts for Chemoselective Asymmetric 1,4-Addition and [3 + 2] Cycloaddition Reactions

The direction of calcium‐catalyzed reaction of Schiff bases with acrylic acid esters and amides depends on the structure of starting compounds leading to either glutamic acid derivatives or substituted pyrrolidines.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2013-10, Vol.44 (41), p.no-no
Hauptverfasser:	Hut'ka, Martin, Tsubogo, Tetsu, Kobayashi, Shu
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylics addition reactions aminocarboxylic acids (hydrazinocarboxylic acids) and esters (acyclic compounds) Calcium Chemical industry cycloaddition reactions diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) pyrrole derivatives
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Beschreibung
Zusammenfassung:	The direction of calcium‐catalyzed reaction of Schiff bases with acrylic acid esters and amides depends on the structure of starting compounds leading to either glutamic acid derivatives or substituted pyrrolidines.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201341027