ChemInform Abstract: Catalytic Asymmetric Synthesis of Cyclic Ethers Containing an [alpha]-Tetrasubstituted Stereocenter

ChemInform Abstract: Catalytic Asymmetric Synthesis of Cyclic Ethers Containing an [alpha]-Tetrasubstituted Stereocenter

An exo-selective cyclization of enantioenriched trisubstituted allenes is developed in the presence of combined Au/Ag catalyst which allows the asymmetric preparation of cyclic ethers containing a tetrasubstituted stereocenter. [PUBLICATION ABSTRACT]

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Veröffentlicht in:ChemInform 2013-09, Vol.44 (38)
Hauptverfasser: Cox, Nick, Uehling, Mycah R, Haelsig, Karl T, Lalic, Gojko
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:An exo-selective cyclization of enantioenriched trisubstituted allenes is developed in the presence of combined Au/Ag catalyst which allows the asymmetric preparation of cyclic ethers containing a tetrasubstituted stereocenter. [PUBLICATION ABSTRACT]
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201338096