Crystal Structure of [Tris(o-phenanthroline-[kappa]2N,N')iron(II)]dinitrate Oxalic Acid Pentahydrate [Fe(phen)3](NO3)2·0.5(H2C2O4)·5H2O
The crystal structure of title compound is consisted by layers of complex cation [Fe(phen)3]2+, oxalic acid and water molecules parallel to [01-1] intercalated by sheet for nitrate anions and the remainder of the water molecules. There is extensive hydrogen bonding leading to a three-dimensional net...
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Veröffentlicht in: | Analytical Sciences ; X-ray Structure and Analysis Online 2007-01, Vol.23, p.65 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The crystal structure of title compound is consisted by layers of complex cation [Fe(phen)3]2+, oxalic acid and water molecules parallel to [01-1] intercalated by sheet for nitrate anions and the remainder of the water molecules. There is extensive hydrogen bonding leading to a three-dimensional network. The compound crystallizes in the triclinic system, spaces group P1 (N[Degree]2), with cell parameters a = 12.661(4)Å, b = 13.045(3)Å, c = 13.444(3)Å, α = 94.90(3)[Degree], β = 117.53(3)[Degree], γ = 101.88(3)[Degree], V = 1884.7(8)Å3, Z = 2, R[I > 2 σ(I)] = 0.0335, wR(F2)[I > 2 σ(I)] = 0.0933. |
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ISSN: | 1348-2238 1883-3578 |
DOI: | 10.2116/analscix.23.x65 |