Crystal Structure of 1-(4-Acetylamidophenyl)-3-(4-carboxyphenyl)triazene

Crystal Structure of 1-(4-Acetylamidophenyl)-3-(4-carboxyphenyl)triazene

The crystal structure of the title compound, C15H14N4O3, reveals the expected trans stereochemistry about the N=N double bond in the diazoamine moiety. The interplanar angle [36.68(6)°] between the terminal phenyl rings indicates that the whole molecule deviates significantly from planarity (r.m.s....

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Veröffentlicht in:Analytical Sciences ; X-ray Structure and Analysis Online 2008, Vol.24, pp.x85-x86
Hauptverfasser: Carlos Henrique Oliveira do AMARAL, HÖRNER, Rosmari, REETZ, Luiz Gustavo Brenner, Leandro Renato Simon de CAMARGO, MACHADO, Flávia Cavalieri, HÖRNER, Manfredo
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container_title Analytical Sciences ; X-ray Structure and Analysis Online
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creator Carlos Henrique Oliveira do AMARAL
HÖRNER, Rosmari
REETZ, Luiz Gustavo Brenner
Leandro Renato Simon de CAMARGO
MACHADO, Flávia Cavalieri
HÖRNER, Manfredo
description The crystal structure of the title compound, C15H14N4O3, reveals the expected trans stereochemistry about the N=N double bond in the diazoamine moiety. The interplanar angle [36.68(6)°] between the terminal phenyl rings indicates that the whole molecule deviates significantly from planarity (r.m.s. deviation = 0.3148 Å). Intermolecular O-H…O classical hydrogen bonds, and hydrogen bonds with a bifurcated geometry generate a three-dimensional molecule arrangement. The distribution of the double-bond character among the N atoms of the diazoamine moiety is unequal, indicating a delocalization of the π electrons over the N=N-N(H) group toward the terminal 4-carboxyphenyl substituent.
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title Crystal Structure of 1-(4-Acetylamidophenyl)-3-(4-carboxyphenyl)triazene
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