Crystal Structure of 1-(4-Acetylamidophenyl)-3-(4-carboxyphenyl)triazene

The crystal structure of the title compound, C15H14N4O3, reveals the expected trans stereochemistry about the N=N double bond in the diazoamine moiety. The interplanar angle [36.68(6)°] between the terminal phenyl rings indicates that the whole molecule deviates significantly from planarity (r.m.s....

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Veröffentlicht in:Analytical Sciences ; X-ray Structure and Analysis Online 2008, Vol.24, pp.x85-x86
Hauptverfasser: Carlos Henrique Oliveira do AMARAL, HÖRNER, Rosmari, REETZ, Luiz Gustavo Brenner, Leandro Renato Simon de CAMARGO, MACHADO, Flávia Cavalieri, HÖRNER, Manfredo
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal structure of the title compound, C15H14N4O3, reveals the expected trans stereochemistry about the N=N double bond in the diazoamine moiety. The interplanar angle [36.68(6)°] between the terminal phenyl rings indicates that the whole molecule deviates significantly from planarity (r.m.s. deviation = 0.3148 Å). Intermolecular O-H…O classical hydrogen bonds, and hydrogen bonds with a bifurcated geometry generate a three-dimensional molecule arrangement. The distribution of the double-bond character among the N atoms of the diazoamine moiety is unequal, indicating a delocalization of the π electrons over the N=N-N(H) group toward the terminal 4-carboxyphenyl substituent.
ISSN:1348-2238
1348-2238
1883-3578
DOI:10.2116/analscix.24.x85