ChemInform Abstract: Versatile Approaches for the Synthesis of Fused-Ring [gamma]-Lactones Utilizing Cyclopropane Intermediates

ChemInform Abstract: Versatile Approaches for the Synthesis of Fused-Ring [gamma]-Lactones Utilizing Cyclopropane Intermediates

Five sequences demonstrate the usefulness for the construction of a range of bi- and tricyclic functionalized lactones with control of stereochemistry and a minimum of synthetic steps, involving an acid-catalyzed cyclopropylester to [gamma]-lactone skeletal rearrangement [PUBLICATION ABSTRACT].

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Veröffentlicht in:ChemInform 2013-08, Vol.44 (34)
Hauptverfasser: Newhouse, Timothy R, Kaib, Philip S. J, Gross, Andrew W, Corey, E. J
Format: Artikel
Sprache:eng
Schlagworte:
Bacteriology
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Zusammenfassung:Five sequences demonstrate the usefulness for the construction of a range of bi- and tricyclic functionalized lactones with control of stereochemistry and a minimum of synthetic steps, involving an acid-catalyzed cyclopropylester to [gamma]-lactone skeletal rearrangement [PUBLICATION ABSTRACT].
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201334092