ChemInform Abstract: Catalytic Oxidative 1,2-Shift in 1,1′-Disubstituted Olefins Using Arene(iodo)sulfonic Acid as the Precatalyst and Oxone as the Oxidant

ChemInform Abstract: Catalytic Oxidative 1,2-Shift in 1,1′-Disubstituted Olefins Using Arene(iodo)sulfonic Acid as the Precatalyst and Oxone as the Oxidant

The new methodology provides concise access to homobenzylic ketones with electron‐donating substituents from disubstituted olefins (IV).

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Veröffentlicht in:ChemInform 2013-07, Vol.44 (31), p.no-no
Hauptverfasser: Purohit, Vikram C., Allwein, Shawn P., Bakale, Roger P.
Format: Artikel
Sprache:eng
Schlagworte:
catalysis
catalysis, phase‐transfer catalysis
cycloalkylphenyl derivatives
ketones (benzene compounds)
phase-transfer catalysis
rearrangements
ring expansion
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Zusammenfassung:The new methodology provides concise access to homobenzylic ketones with electron‐donating substituents from disubstituted olefins (IV).
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201331029