Back Cover: Metal-Free HB(C6F5)2-Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane-Mediated Ï-Bond Metathesis (Angew. Chem. Int. Ed. 29/2013)

Back Cover: Metal-Free HB(C6F5)2-Catalyzed Hydrogenation of Unfunctionalized Olefins and Mechanism Study of Borane-Mediated Ï-Bond Metathesis (Angew. Chem. Int. Ed. 29/2013)

Out with the metal: Metal-free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane-mediated σ-bond metathesis, which has been investigated both experimentally and theoretically....

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Veröffentlicht in:Angewandte Chemie International Edition 2013-07, Vol.52 (29), p.7606
Hauptverfasser: Wang, Yuwen, Chen, Weiqiang, Lu, Zhenpin, Li, Zhen Hua, Wang, Huadong
Format: Artikel
Sprache:eng
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Zusammenfassung:Out with the metal: Metal-free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane-mediated σ-bond metathesis, which has been investigated both experimentally and theoretically.
ISSN:1433-7851
1521-3773