Propargyl Anthranilate Derivatives and Their Application in the Synthesis of Rings Containing 1,2,3-Triazolo Motifs

Propargyl Anthranilate Derivatives and Their Application in the Synthesis of Rings Containing 1,2,3-Triazolo Motifs

Propargyl anthranilate, a simple and less studied molecule with several reactive sites, is widely applicable in organic synthesis. An optimized synthesis of this compound and its derivatives and the preparation of azide derivatives are described. The optimized process of the known intramolecular cyc...

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Veröffentlicht in:Journal of heterocyclic chemistry 2013-05, Vol.50 (3), p.528-533
Hauptverfasser: Hradilová, Ludmila, Grepl, Martin, Hlaváč, Jan, Lyčka, Antonín, Hradil, Pavel
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container_end_page 533
container_issue 3
container_start_page 528
container_title Journal of heterocyclic chemistry
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creator Hradilová, Ludmila
Grepl, Martin
Hlaváč, Jan
Lyčka, Antonín
Hradil, Pavel
description Propargyl anthranilate, a simple and less studied molecule with several reactive sites, is widely applicable in organic synthesis. An optimized synthesis of this compound and its derivatives and the preparation of azide derivatives are described. The optimized process of the known intramolecular cyclization is described, and the unknown intermolecular cyclizations of these azido derivatives and formation of a macrocycle are discussed.
doi_str_mv 10.1002/jhet.1514
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title Propargyl Anthranilate Derivatives and Their Application in the Synthesis of Rings Containing 1,2,3-Triazolo Motifs
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