ChemInform Abstract: Nitroalkenes as Carbonyl Surrogates in Arylmethyl-homoallylic Alcohol Forming One-Pot Allylation Reactions in Water

ChemInform Abstract: Nitroalkenes as Carbonyl Surrogates in Arylmethyl-homoallylic Alcohol Forming One-Pot Allylation Reactions in Water

The reaction is proposed to proceed via initial generation of a nitrostyrene radical anion by SET from tin followed by bisprotonation leading to a nitronic acid.

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Veröffentlicht in:ChemInform 2013-06, Vol.44 (23), p.no-no
Hauptverfasser: Lin, Mei-Huey, Lin, Wei-Cheng, Liu, Han-Jun, Chuang, Tsung-Hsun
Format: Artikel
Sprache:eng
Schlagworte:
Alcohol
alcohols (acyclic compounds)
C-C bond formation
intermediates (and their reactions)
radical reactions
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Zusammenfassung:The reaction is proposed to proceed via initial generation of a nitrostyrene radical anion by SET from tin followed by bisprotonation leading to a nitronic acid.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201323036