ChemInform Abstract: Direct [alpha]-Functionalization of Simple Aldehydes via Oxidative N-Heterocyclic Carbene Catalysis

ChemInform Abstract: Direct [alpha]-Functionalization of Simple Aldehydes via Oxidative N-Heterocyclic Carbene Catalysis

The protocol applies a stoichiometric amount of quinone as an oxidant and proceeds via oxidative enolate formation to afford [gamma]-lactones with high yields and complete enantioselectivity. [PUBLICATION ABSTRACT]

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2013-05, Vol.44 (20), p.no
Hauptverfasser: Mo, Junming, Yang, Ruojie, Chen, Xingkuan, Tiwari, Bhoopendra, Chi, Yonggui Robin
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The protocol applies a stoichiometric amount of quinone as an oxidant and proceeds via oxidative enolate formation to afford [gamma]-lactones with high yields and complete enantioselectivity. [PUBLICATION ABSTRACT]
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201320152