ChemInform Abstract: Hypervalent Iodine Catalyzed Hofmann Rearrangement of Carboxamides Using Oxone as Terminal Oxidant

ChemInform Abstract: Hypervalent Iodine Catalyzed Hofmann Rearrangement of Carboxamides Using Oxone as Terminal Oxidant

The reaction is proposed to proceed via electron‐deficient active species generated from hydroxy(phenyl)iodonium ion or hypervalent aminoiodane and (F3C)2CH—OH.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2013-05, Vol.44 (19), p.no-no
Hauptverfasser: Yoshimura, Akira, Middleton, Kyle R., Luedtke, Matthew W., Zhu, Chenjie, Zhdankin, Viktor V.
Format: Artikel
Sprache:eng
Schlagworte:
carbamic acid derivatives (acyclic compounds)
carbamic acid derivatives (benzene compounds)
catalysis
catalysis, phase‐transfer catalysis
phase-transfer catalysis
rearrangements
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Beschreibung
Zusammenfassung:The reaction is proposed to proceed via electron‐deficient active species generated from hydroxy(phenyl)iodonium ion or hypervalent aminoiodane and (F3C)2CH—OH.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201319030