ChemInform Abstract: Highly Enantio- and Diastereoselective Generation of Two Quaternary Centers in Spirocyclopropanation of Oxindole Derivatives

The reactions with 2‐chloroacetoacetate (II), 3‐chloroacetylacetone (IV) and dimethylchloromalonate (VI) proceed with good to excellent dia‐ and high enantioselectivities.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2013-04, Vol.44 (15), p.no-no
Hauptverfasser:	Noole, Artur, Sucman, Natalia S., Kabeshov, Mikhail A., Kanger, Tonis, Macaev, Fliur Z., Malkov, Andrei V.
Format:	Artikel
Sprache:	eng
Schlagworte:	cyclopropanation reactions diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) indole derivatives indole derivatives, isoindole derivatives isoindole derivatives organocatalysis spirocyclic compounds
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Beschreibung
Zusammenfassung:	The reactions with 2‐chloroacetoacetate (II), 3‐chloroacetylacetone (IV) and dimethylchloromalonate (VI) proceed with good to excellent dia‐ and high enantioselectivities.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201315101