ChemInform Abstract: Chelation-Controlled Addition of Organozincs to [alpha]-Chloro Aldimines

ChemInform Abstract: Chelation-Controlled Addition of Organozincs to [alpha]-Chloro Aldimines

An unusual chelation-controlled pathway is revealed based on experimental and computational investigations: binding of the [alpha]-chloro aldimines N,O and Cl atom to zinc reverses the selectivity predicted by the Cornforth--Evans model. [PUBLICATION ABSTRACT]

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Veröffentlicht in:ChemInform 2013-04, Vol.44 (15), p.no
Hauptverfasser: Stanton, Gretchen R, Norrby, Per-Ola, Carroll, Patrick J, Walsh, Patrick J
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:An unusual chelation-controlled pathway is revealed based on experimental and computational investigations: binding of the [alpha]-chloro aldimines N,O and Cl atom to zinc reverses the selectivity predicted by the Cornforth--Evans model. [PUBLICATION ABSTRACT]
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201315021