Catalytic Conversion of Nitriles into Secondary- and Tertiary Amides

Catalytic Conversion of Nitriles into Secondary- and Tertiary Amides

A nice couple: The coupling of nitriles with amines in the presence of water is catalyzed by a combination of zinc triflate and hydroxylamine hydrochloride to give the corresponding amides in good yields.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ChemCatChem 2013-02, Vol.5 (2), p.435-438
Hauptverfasser: Davulcu, Simge, Allen, C. Liana, Milne, Kirstie, Williams, Jonathan M. J.
Format: Artikel
Sprache:eng
Schlagworte:
amides
amidines
amines
homogeneous catalysis
zinc
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A nice couple: The coupling of nitriles with amines in the presence of water is catalyzed by a combination of zinc triflate and hydroxylamine hydrochloride to give the corresponding amides in good yields.
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201200406