ChemInform Abstract: Catalytic Hydrogen Atom Transfer (HAT) for Sustainable and Diastereoselective Radical Reduction

ChemInform Abstract: Catalytic Hydrogen Atom Transfer (HAT) for Sustainable and Diastereoselective Radical Reduction

A readily available nontoxic silane is used as terminal reductant for epoxides that are opened by in situ formed bifunctional titanocene(III) hydride catalysts.

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Veröffentlicht in:ChemInform 2013-01, Vol.44 (2), p.no-no
Hauptverfasser: Gansaeuer, Andreas, Klatte, Max, Braendle, Gerhard M., Friedrich, Joachim
Format: Artikel
Sprache:eng
Schlagworte:
alcohols (acyclic compounds)
alcohols (benzene compounds)
cyclohexane derivatives
radical reactions
ring opening reactions
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Zusammenfassung:A readily available nontoxic silane is used as terminal reductant for epoxides that are opened by in situ formed bifunctional titanocene(III) hydride catalysts.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201302032