ChemInform Abstract: Synthesis of 1,2-Bisalkylidenecyclopentanes from 1,6-Allenynes via Stereoselective Addition of Nucleophiles to Ruthenacyclopentenes

ChemInform Abstract: Synthesis of 1,2-Bisalkylidenecyclopentanes from 1,6-Allenynes via Stereoselective Addition of Nucleophiles to Ruthenacyclopentenes

A new type of reaction of ruthenacyclopentenes derived from 1,6‐allenynes (I) and (III) toward nucleophiles, such as alcohols (IV) and (VI), is presented.

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Veröffentlicht in:ChemInform 2012-08, Vol.43 (33), p.no-no
Hauptverfasser: Saito, Nozomi, Kohyama, Yuh, Tanaka, Yuki, Sato, Yoshihiro
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Sprache:eng
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cyclopentane derivatives
e/z-selectivity (incl. e/z-isomerism)
ring closure reactions
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container_title ChemInform
container_volume 43
creator Saito, Nozomi
Kohyama, Yuh
Tanaka, Yuki
Sato, Yoshihiro
description A new type of reaction of ruthenacyclopentenes derived from 1,6‐allenynes (I) and (III) toward nucleophiles, such as alcohols (IV) and (VI), is presented.
doi_str_mv 10.1002/chin.201233059
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subjects cyclopentane derivatives
e/z-selectivity (incl. e/z-isomerism)
ring closure reactions
title ChemInform Abstract: Synthesis of 1,2-Bisalkylidenecyclopentanes from 1,6-Allenynes via Stereoselective Addition of Nucleophiles to Ruthenacyclopentenes
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