ChemInform Abstract: Asymmetric Synthesis of Dihydroindans by Convergent Alkoxide-Directed Metallacycle-Mediated Bond Formation

Depending on the substitution pattern, the reaction of internal alkynes with 4‐hydroxy‐1,6‐enynes can lead to the products of alkene—alkyne coupling, alkyne—alkyne coupling or [2 + 2 + 2] annulation.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2012-08, Vol.43 (33), p.no-no
Hauptverfasser:	Greszler, Stephen N., Reichard, Holly A., Micalizio, Glenn C.
Format:	Artikel
Sprache:	eng
Schlagworte:	diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) indan derivatives ring closure reactions
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Beschreibung
Zusammenfassung:	Depending on the substitution pattern, the reaction of internal alkynes with 4‐hydroxy‐1,6‐enynes can lead to the products of alkene—alkyne coupling, alkyne—alkyne coupling or [2 + 2 + 2] annulation.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201233104